АНИОН-РАДИКАЛЬНАЯ КОНДЕНСАЦИЯ КЕТИЛА И ДИАНИОНА БЕНЗОФЕНОН-КАЛИЯ С АНИЛИНОМ
Abstract
In the interaction of K-ketyl and the benzophenone dianion with condensation occurs
with aniline, leading to the formation of a Schiff base of diphenylmethinaniline. It flows sideways
cleavage of the C-C bond of K-ketyl benzophenone to form benzoic acid, as well as the reduction
product – benzhydrol
Keywords
anion-radical,, ketyl,, dianion,How to Cite
References
Д.А.Тураева., А.С.Курбатова. ,Ю.В.Курбатов // ЖОрХ, 1993, Т.29,
Вып.8 С.1588-1591
D.A.Turaeva., Yu.V.Kurbatov // J.Org.chem. Sankt-Peterburg – 1999. Vol.35. P.1116-1117.
Turaeva D.A., Kurbatova A.S., Kurbatov Yu.V. // Book of Abstracts 10th IUPAC Symposium
on Organometallic Chemistry directed towards Organic Synthesis.Versailles, France,
P.490.
Bachmann V.E. // J. Am. Chem. Soc. 1933. Vol. 55. P.2827-2830.
Охлобыстин О.Ю. Перенос электрона в органических реакциях. Ростов-на-Дону:
Ростов. Гос. ун-та, 1974, с. 48.
Foerst W. Newer Methods of Preparative Organic Chemistry. Academic, New-York,
P.246.
Мендкович А.С., Гультяй В.П. Теоретические основы химии органических анион-
радикалов. М.: Наука, 1990, с. 69.
Тодрес З.В. Ион-радикалы в органическом синтезе. М.: Химия, 1986, с. 20.
Денисов Е.Т. Кинетика гомогенных химических реакций. М.: Высшая школа, 1978,
с. 127.
Billman J.H., Tai K.M., J. Org. Chem., 1958, Vol.23. P. 535
License
Copyright (c) 2023 Дилбар Тураева
This work is licensed under a Creative Commons Attribution 4.0 International License.
The content published on the International Scientific and Current Research Conferences platform, including conference papers, abstracts, and presentations, is made available under an open-access model. Users are free to access, share, and distribute this content, provided that proper attribution is given to the original authors and the source.
